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ASYMMETRIC SYNTHESES OF ETHYL (S)-(+)-2-METHYLHEPT-4-YNOATE USING BOTH ENANTIOMERS OF THE CHIRAL IRON AUXILIARY [(ETA-5-C5H5)FE(CO)(PPH3)]

Abstract:
The asymmetric syntheses of ethyl (S)-(+)-2-methylhept-4-ynoate via double alkylations of the homochiral acetate equivalents (R)- and (S)-[(η5-C5H5)Fe(CO)(PPh3)COCH3] are described. © 1991.
Publication status:
Published

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Publisher copy:
10.1016/S0957-4166(00)86147-9

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Journal:
TETRAHEDRON-ASYMMETRY More from this journal
Volume:
2
Issue:
10
Pages:
1075-1082
Publication date:
1991-01-01
DOI:
EISSN:
1362-511X
ISSN:
0957-4166


Language:
English
Pubs id:
pubs:110734
UUID:
uuid:b4e4ae71-acb7-43cd-9d21-7a1da815f56b
Local pid:
pubs:110734
Source identifiers:
110734
Deposit date:
2012-12-19

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