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Structural chemistry of Ln(2)BaLiRuO(7) (Ln = La, Pr)

Abstract:

Polycrystalline samples of the n=2 Ruddlesden-Popper compositions Pr 2BaLiRuO7 and La2BaLiRuO7 have been synthesised by solid-state techniques and characterised by X-ray and neutron diffraction, electron microscopy and 7Li MAS NMR. The 6-coordinate sites are occupied by a 1:1 ordered arrangement of Li and Ru, the 12-coordinate sites within the perovskite-like blocks are occupied by Ba, and the cation sites on the block edges are occupied by La or Pr. Although the cation ordering is maintained...

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Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
SOLID STATE SCIENCES
Volume:
8
Issue:
3-4
Pages:
280-288
Publication date:
2006-01-01
DOI:
ISSN:
1293-2558
URN:
uuid:b3f0289e-3b1a-488c-a906-5063ef28854c
Source identifiers:
39941
Local pid:
pubs:39941
Language:
English

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