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Synthesis of titanium borylimido compounds supported by diamide-amine ligands and their reactions with alkynes

Abstract:

We report a combined synthetic, mechanistic, and computational (DFT) study of the synthesis of new diamide-amine-supported titanium borylimides and their reactions with TolCCH and ArFCCH (Tol = 4-C6H4Me, ArF = C6F5). Reaction of Ti{NB(NAr′CH)2}Cl2(py)3 (Ar′ = 2,6-C6H3iPr2) with Li2N2RNMe (N2RNMe = MeN(CH2CH2NR)2) or Li2N2Npy (N2Npy = (2-C5H4N)CMe(CH2NSiMe3)2) afforded the borylimides Ti(N2RNMe){NB(NAr′CH)2}(py) (R = SiMe3 (9), ArF (10), or iPr (11)) and Ti(N2Npy){NB(NAr′CH)2}(py) (21). Compou...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted Manuscript

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Publisher copy:
10.1021/acs.organomet.8b00250

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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry; Inorganic Chemistry
Oxford college:
St Edmund Hall
Publisher:
American Chemical Society Publisher's website
Journal:
Organometallics Journal website
Volume:
37
Issue:
20
Pages:
3558–3572
Publication date:
2018-06-15
Acceptance date:
2018-06-01
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
Pubs id:
pubs:854690
URN:
uri:b363bb82-e454-4ad6-9ede-355aa7d67aae
UUID:
uuid:b363bb82-e454-4ad6-9ede-355aa7d67aae
Local pid:
pubs:854690

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