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Structure and bonding in endohedral transition metal clusters

Abstract:

Endohedral clusters of the tetrel elements, M@En, provide a diverse platform for exploring chemical bonding, simply because the cluster does not necessarily depend on strong M–E bonding for its integrity. The interaction between the metal and the cluster can therefore range from strongly covalent all the way to cases where the metal is simply trapped inside the cage by virtue of the strong E-E bonds, with little or no direct bonding. This spectrum of bond types leads to unusual structural, sp...

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Publication status:
Published
Peer review status:
Peer reviewed

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Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Subgroup:
Inorganic Chemistry
More by this author
Institution:
University of Oxford
Division:
MPLS Division
Department:
Chemistry
Subgroup:
Inorganic Chemistry
Oxford college:
New College
ORCID:
0000-0002-8991-1921
Publisher:
Elsevier Publisher's website
Volume:
73
Pages:
265-304
Series:
Advances in Inorganic Chemistry
Host title:
Computational Chemistry
Publication date:
2019-01-14
DOI:
ISSN:
0898-8838
Pubs id:
pubs:972826
URN:
uri:b361cf94-fb6a-4b00-9733-9ced1a5d868a
UUID:
uuid:b361cf94-fb6a-4b00-9733-9ced1a5d868a
Local pid:
pubs:972826
ISBN:
978-0-12-815728-2

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