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The influence of ligands in Pinhey phenylation reactions using lead(IV) tetracarboxylates

Abstract:
Lead(IV) tetracarboxylates, prepared from achiral and chiral carboxylic acids, have been shown to undergo metal-metal exchange with phenylboronic acid, and the phenyllead(IV) carboxylates thus generated in situ can be used for Pinhey phenylation reactions. Although the yields of these reactions are generally moderate to good, only low levels of asymmetric induction at best were observed. Possible reasons for this lack of enantioselectivity are discussed.
Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Prottey, SC More by this author
Thompson, RM More by this author
Journal:
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume:
534
Issue:
1-2
Pages:
195-205
Publication date:
1997-04-28
DOI:
ISSN:
0022-328X
URN:
uuid:b280f62a-7dd7-4213-b513-00ad8e015c6d
Source identifiers:
45596
Local pid:
pubs:45596

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