Journal article

C-C sigma complexes of rhodium.

Abstract:: In this article, the complexes [Rh(Binor-S')(PR3)][BAr(4)(F)] (R = (i)Pr, Cy, C(5)H(9)) are described. A combination of x-ray crystallography, NMR spectroscopy, density functional theory, and "atoms in molecules" calculations unequivocally demonstrates that the complexes contain rare examples of metal...C-C agostic interactions. Moreover, they are fluxional on the NMR time scale, undergoing rapid and reversible C-C activation. Kinetic data and calculations point to a bismetallacyclobutane, Rh(V), intermediate.

Publication status:: Published

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APA Style

Brayshaw, S., Sceats, E., Green, J., & Weller, A. (2007). C-C sigma complexes of rhodium. Proceedings of the National Academy of Sciences of the United States of America, 104(17), 6921–6926.

MLA Style

Brayshaw, S., et al. “C-C Sigma Complexes of Rhodium.” Proceedings of the National Academy of Sciences of the United States of America, vol. 104, no. 17, 2007, pp. 6921–26.

Chicago Style

Brayshaw, S, E Sceats, J Green, and A Weller. 2007. “C-C Sigma Complexes of Rhodium.” Proceedings of the National Academy of Sciences of the United States of America 104 (17): 6921–26.
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Publisher copy:: 10.1073/pnas.0609824104

Authors

+ Brayshaw, S More by this author

Role:: Author

+ Sceats, E More by this author

Role:: Author

+ Green, J More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

+ Weller, A More by this author

Institution:: University of Oxford
Division:: MPLS
Department:: Chemistry
Sub department:: Inorganic Chemistry
Role:: Author

Journal:: Proceedings of the National Academy of Sciences of the United States of America More from this journal
Volume:: 104
Issue:: 17
Pages:: 6921-6926
Publication date:: 2007-04-01
DOI:: 10.1073/pnas.0609824104
EISSN:: 1091-6490
ISSN:: 0027-8424

Language:: English
Keywords:: C-C activation

density functional theory
Pubs id:: pubs:40328
UUID:: uuid:b27f1472-3389-473f-b293-8f34909ceb69
Local pid:: pubs:40328
Source identifiers:: 40328
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 2007

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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