Reaction of NiCl2 with NaTaO3 leads the formation of the perovskite phase Ni(0.5)TaO3, via a topochemical nickel-for-sodium cation exchange in which the framework of apex-linked TaO6 octahedra present in the parent phase is retained. Neutron powder diffraction data indicate Ni(0.5)TaO3 adopts a structure analogous to the paraelectric phase of LiTaO3, with triclinic P1 crystallographic symmetry. Although Ni(0.5)TaO3 has features which make it a good candidate phase for magnetoelectric multifer...Expand abstract
- Publication status:
- Publisher copy:
- Copyright date:
Cation exchange in a 3D perovskite-synthesis of Ni(0.5)TaO₃.
If you are the owner of this record, you can report an update to it here: Report update to this record