- Abstract:
-
Reaction of NiCl2 with NaTaO3 leads the formation of the perovskite phase Ni(0.5)TaO3, via a topochemical nickel-for-sodium cation exchange in which the framework of apex-linked TaO6 octahedra present in the parent phase is retained. Neutron powder diffraction data indicate Ni(0.5)TaO3 adopts a structure analogous to the paraelectric phase of LiTaO3, with triclinic P1 crystallographic symmetry. Although Ni(0.5)TaO3 has features which make it a good candidate phase for magnetoelectric multifer...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1021/ic500881v
-
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- Publisher:
- American Chemical Society
- Journal:
- Inorganic chemistry
- Volume:
- 53
- Issue:
- 15
- Pages:
- 8020-8024
- Publication date:
- 2014-08-05
- DOI:
- EISSN:
-
1520-510X
- ISSN:
-
0020-1669
- URN:
-
uuid:b23c29be-f20d-4127-b7d9-db38634b9811
- Source identifiers:
-
477708
- Local pid:
- pubs:477708
- Language:
- English
- Copyright date:
- 2014
Journal article
Cation exchange in a 3D perovskite-synthesis of Ni(0.5)TaO₃.
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