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Cation exchange in a 3D perovskite-synthesis of Ni(0.5)TaO₃.

Abstract:

Reaction of NiCl2 with NaTaO3 leads the formation of the perovskite phase Ni(0.5)TaO3, via a topochemical nickel-for-sodium cation exchange in which the framework of apex-linked TaO6 octahedra present in the parent phase is retained. Neutron powder diffraction data indicate Ni(0.5)TaO3 adopts a structure analogous to the paraelectric phase of LiTaO3, with triclinic P1 crystallographic symmetry. Although Ni(0.5)TaO3 has features which make it a good candidate phase for magnetoelectric multifer...

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Publication status:
Published

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Publisher copy:
10.1021/ic500881v

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Publisher:
American Chemical Society
Journal:
Inorganic chemistry
Volume:
53
Issue:
15
Pages:
8020-8024
Publication date:
2014-08-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:b23c29be-f20d-4127-b7d9-db38634b9811
Source identifiers:
477708
Local pid:
pubs:477708
Language:
English

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