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Amino-borane oligomers bound to a Rh(I) metal fragment.

Abstract:
Coordination complexes of previously observed intermediates, H(3)B.NMe(2)BH(2).NMe(2)H and [H(2)BNMeH](3), in the transition metal catalysed dehydrocoupling of H(3)B.NMe(2)H and H(3)B.NMeH(2) have been isolated and structurally characterised using the [Rh{PR'(2)(eta(2)-C(5)H(7))}](+) fragment. Their onward reactivity shows that further dehydrogenation is not a simple intramolecular process.
Publication status:
Published

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Publisher copy:
10.1039/c003055d

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
Chemical communications (Cambridge, England)
Volume:
46
Issue:
18
Pages:
3092-3094
Publication date:
2010-05-05
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
URN:
uuid:b1b7db32-0d82-42fa-ab5e-ff298d9fb44f
Source identifiers:
54663
Local pid:
pubs:54663
Language:
English

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