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Bimetallic Lanthanide Complexes Derived from Macrocycle-Appended m-Xylyl Derivatives: Synthesis and Spectroscopic Properties

Abstract:
A series of bimetallic lanthanide complexes was prepared from a bimacrocyclic system in which two DO3A units are linked by a m-xylyl unit appended with either a NO2 or an NH2 group (DO3A=1,4,7,10-tetraazacyclododecane-1,4,7-triacetic acid). The Nd-, Eu-, Tb- and Yb-complexes were all luminescent: time-resolved studies indicated that the lipophilic xylyl group restricts close approach of H2O to the metal centre. © 2009 Verlag Helvetica Chimica Acta AG.
Publication status:
Published

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Publisher copy:
10.1002/hlca.200900141

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
HELVETICA CHIMICA ACTA
Volume:
92
Issue:
11
Pages:
2427-2438
Publication date:
2009-01-01
DOI:
EISSN:
1522-2675
ISSN:
0018-019X
URN:
uuid:b1a8d977-a20c-48cd-9d3b-3972eefd8027
Source identifiers:
41490
Local pid:
pubs:41490
Language:
English

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