- Abstract:
- A series of bimetallic lanthanide complexes was prepared from a bimacrocyclic system in which two DO3A units are linked by a m-xylyl unit appended with either a NO2 or an NH2 group (DO3A=1,4,7,10-tetraazacyclododecane-1,4,7-triacetic acid). The Nd-, Eu-, Tb- and Yb-complexes were all luminescent: time-resolved studies indicated that the lipophilic xylyl group restricts close approach of H2O to the metal centre. © 2009 Verlag Helvetica Chimica Acta AG.
- Publication status:
- Published
- Publisher copy:
- 10.1002/hlca.200900141
-
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- Journal:
- HELVETICA CHIMICA ACTA
- Volume:
- 92
- Issue:
- 11
- Pages:
- 2427-2438
- Publication date:
- 2009-01-01
- DOI:
- EISSN:
-
1522-2675
- ISSN:
-
0018-019X
- URN:
-
uuid:b1a8d977-a20c-48cd-9d3b-3972eefd8027
- Source identifiers:
-
41490
- Local pid:
- pubs:41490
- Language:
- English
- Copyright date:
- 2009
Journal article
Bimetallic Lanthanide Complexes Derived from Macrocycle-Appended m-Xylyl Derivatives: Synthesis and Spectroscopic Properties
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