Journal article icon

Journal article

Spectroscopic investigations of bis(sulfoximine) copper(II) complexes and their relevance in asymmetric catalysis.

Abstract:

The structure of Cu(II) complex 3 formed within the course of a stereoselective Diels-Alder reaction was investigated by EXAFS, CW-EPR at X- and W-band, HYSCORE, pulsed ENDOR, and UV-vis spectroscopy. The experimental techniques indicate that the chiral bis(sulfoximine) ligand (S,S)-1 and the dienophile form a tetragonally distorted complex in CH(2)Cl(2). The ligand binds to the Cu(II) center via the imine nitrogens, whereas the dienophile interacts via the carbonyl oxygen atoms. The addition...

Expand abstract
Publication status:
Published

Actions


Access Document


Publisher copy:
10.1021/ja027870w

Authors


Gescheidt, G More by this author
Palivan, C More by this author
Neshchadin, D More by this author
Expand authors...
Journal:
Journal of the American Chemical Society
Volume:
125
Issue:
20
Pages:
6222-6227
Publication date:
2003-05-05
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
URN:
uuid:b0c55e37-5c88-4bb5-adbf-5fbf89fdc41a
Source identifiers:
326062
Local pid:
pubs:326062
Language:
English

Terms of use


Metrics



If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP