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Evidence for micellar structure in the gas phase.

Abstract:

We have compared micelles, reverse micelles, and reverse micelles encapsulating myoglobin using electrospray mass spectrometry. To enable a direct comparison, the same surfactant (cetyltrimethylammonium bromide (CTAB)) was used in each case and micelle formation was controlled by manipulating the aqueous and organic phases. Tandem mass spectra of the resulting micelle preparations reveal differences in the ions that dissociate: those that dissociate from regular micelles have undergone >90...

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Publication status:
Published

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Publisher copy:
10.1021/ja067820h

Authors


Robinson, CV More by this author
Journal:
Journal of the American Chemical Society
Volume:
129
Issue:
28
Pages:
8740-8746
Publication date:
2007-07-05
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
URN:
uuid:b03a775d-5329-4e41-bebe-5ec7e626b86a
Source identifiers:
59302
Local pid:
pubs:59302

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