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Cyclodextrin-threaded conjugated polyrotaxanes as insulated molecular wires with reduced interstrand interactions.

Abstract:

Control of intermolecular interactions is crucial to the exploitation of molecular semiconductors for both organic electronics and the viable manipulation and incorporation of single molecules into nano-engineered devices. Here we explore the properties of a class of materials that are engineered at a supramolecular level by threading a conjugated macromolecule, such as poly(para-phenylene), poly(4,4'-diphenylene vinylene) or polyfluorene through alpha- or beta-cyclodextrin rings, so as to re...

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Publication status:
Published

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Publisher copy:
10.1038/nmat750

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Journal:
Nature materials
Volume:
1
Issue:
3
Pages:
160-164
Publication date:
2002-11-05
DOI:
EISSN:
1476-4660
ISSN:
1476-1122
URN:
uuid:afb2d9d6-48a6-4963-894b-fa9db6266d26
Source identifiers:
111
Local pid:
pubs:111

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