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Salt and isotope effects upon a multistep electrode reaction: the reduction of nitromethane on mercury

Abstract:

The reduction of nitromethane has been studied by impedance voltammetry at various water activities using NaClO4 as the base electrolyte. The impedance analysis conforms well to an EC-C-eee mechanism, and the rate constants for the three rate determining steps are obtained together with the standard potential for the first reduction process (EC). On the other hand, the results obtained for the reduction of deuterated nitromethane in 1 M NaCl + D2O solutions are compared with the ones obtained...

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Publication status:
Published

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Publisher:
Elsevier Sequoia SA
Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
474
Issue:
1
Pages:
60-68
Publication date:
1999-09-16
DOI:
ISSN:
0022-0728
URN:
uuid:afa83836-2231-4413-a654-6802fd083b3b
Source identifiers:
37237
Local pid:
pubs:37237

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