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Supramolecular nesting of cyclic polymers.

Abstract:

Advances in template-directed synthesis make it possible to create artificial molecules with protein-like dimensions, directly from simple components. These synthetic macromolecules have a proclivity for self-organization that is reminiscent of biopolymers. Here, we report the synthesis of monodisperse cyclic porphyrin polymers, with diameters of up to 21 nm (750 C–C bonds). The ratio of the intrinsic viscosities for cyclic and linear topologies is 0.72, indicating that these polymers behave ...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1038/NCHEM.2182

Authors


Publisher:
Springer Nature
Journal:
Nature Chemistry More from this journal
Publication date:
2015-02-16
Acceptance date:
2015-01-13
DOI:
EISSN:
1755-4349
ISSN:
1755-4330
Language:
English
Keywords:
Pubs id:
pubs:517775
UUID:
uuid:af5b5950-1e3e-4104-a80a-2f19bdd188c8
Local pid:
pubs:517775
Source identifiers:
517775
Deposit date:
2015-10-07

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