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Complex magnetic order in topochemically reduced Rh(I)/Rh(III) LaM0.5Rh0.5O2.25 (M = Co, Ni) phases

Abstract:

Topochemical reduction of the cation-disordered perovskite oxides LaCo0.5Rh0.5O3 and LaNi0.5Rh0.5O3 with Zr yields the partially anion-vacancy ordered phases LaCo0.5Rh0.5O2.25 and LaNi0.5Rh0.5O2.25, respectively. Neutron diffraction and Hard X-ray photoelectron spectroscopy (HAXPES) measurements reveal that the anion-deficient phases contain Co1+/Ni

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1021/acs.inorgchem.2c02747

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
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Role:
Author
ORCID:
0000-0002-9599-0531
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Role:
Author
ORCID:
0000-0002-3747-3763
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Role:
Author
ORCID:
0000-0001-5966-5929
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Name:
Engineering and Physical Sciences Research Council
Grant:
EP/T027991/1
Publisher:
American Chemical Society
Journal:
Inorganic Chemistry More from this journal
Volume:
61
Issue:
39
Pages:
15686-15692
Place of publication:
United States
Publication date:
2022-09-21
Acceptance date:
2022-09-13
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
Pmid:
36129165
Language:
English
Keywords:
Pubs id:
1279749
Local pid:
pubs:1279749
Deposit date:
2023-01-16

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