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New Ionophoric Calix[4]diquinones: Coordination Chemistry, Electrochemistry, and X-ray Crystal Structures.

Abstract:

A new library of ionophoric p-tert-butylcalix[4]diquinones containing ester (1), primary, secondary, and tertiary amide (2-4), and crown ether (5) substituents has been synthesized by treatment of the respective 1,3-bis-substituted p-tert-butylcalix[4]arene with Tl(OCOCF(3))(3) in trifluoroacetic acid. The structures of the free ligands 1 and 2, a p-tert-butylcalix[4]diquinone bridged at the lower rim by two linked veratrole groups (7), and a previously synthesized p-tert-butylcalix[4]diquino...

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Publication status:
Published

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Publisher copy:
10.1021/ic9704851

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
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Journal:
Inorganic chemistry
Volume:
36
Issue:
25
Pages:
5880-5893
Publication date:
1997-12-05
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
URN:
uuid:ae7093f8-0dda-4370-99fe-46857d091efc
Source identifiers:
31978
Local pid:
pubs:31978
Language:
English

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