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Journal article

Synthesis and luminescence properties of dinuclear lanthanide complexes derived from covalently linked macrocyclic ligands

Abstract:
A series of homo-binuclear lanthanide complexes have been prepared from DO3A derived systems containing seven-coordinate binding domains linked via an aromatic. The luminescence properties of xylyl bridged complexes show that the lanthanide ions behave as isolated centres, while the combination of the lanthanide contraction and the lipophilicity of the linker group limits inner-sphere hydration around the metal centres for later lanthanides such as ytterbium.
Publication status:
Published

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Publisher copy:
10.1039/b309115e

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
DALTON TRANSACTIONS
Issue:
19
Pages:
3780-3784
Publication date:
2003-01-01
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
Source identifiers:
38754
Language:
English
Pubs id:
pubs:38754
UUID:
uuid:ae6425dc-261b-4264-809c-a9b9698fb0d8
Local pid:
pubs:38754
Deposit date:
2012-12-19

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