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Migratory insertion of [B(C6F5)2] into C-H bonds: CO promoted transfer of the boryl fragment.

Abstract:
The reaction of (eta(5)-C5H5)Fe(CO)2B(C6F5)2 with CO has been shown to proceed via ligand substitution at the metal with accompanying transfer of the boryl fragment (via C-H insertion) to the Cp ring, thereby generating the zwitterion [eta(5)-C5H4B(C6F5)2H]Fe(CO)3 in quantitative yield.
Publication status:
Published

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Publisher copy:
10.1039/b604141h

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Al-Fawaz, A More by this author
Horton, PN More by this author
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Journal:
Chemical communications (Cambridge, England)
Issue:
24
Pages:
2578-2580
Publication date:
2006-06-05
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
URN:
uuid:ae09890f-89dd-41dd-b215-d30b05eae7e8
Source identifiers:
46041
Local pid:
pubs:46041
Language:
English

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