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The chemistry of the 2-Phosphaethynolate anion

Abstract:

In all likelihood the first synthesis of the phosphaethynolate anion, PCO- , was performed in 1894 when NaPH2 was reacted with CO in an attempt to make Na(CP) accompanied by elimination of water. This reaction was repeated 117 years later when it was discovered that Na(OCP) and H2 are the products of this remarkable transformation. Li(OCP) was synthesized and fully characterized in 1992 but this salt proved to be too unstable to allow for a detailed investigation of its chemistry. It was not ...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1002/anie.201803888

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Oxford college:
Lady Margaret Hall
Role:
Author
ORCID:
0000-0002-7311-1663
More by this author
Role:
Author
ORCID:
0000-0002-1531-8906
Publisher:
Wiley
Journal:
Angewandte Chemie International Edition More from this journal
Volume:
57
Issue:
52
Pages:
16968-16994
Publication date:
2018-05-17
Acceptance date:
2018-05-15
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
Pmid:
29770548
Language:
English
Keywords:
Pubs id:
pubs:946685
UUID:
uuid:ad9be566-ca10-4393-8503-0e3d1150ce1a
Local pid:
pubs:946685
Source identifiers:
946685
Deposit date:
2019-02-18

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