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Synthesis and Structure of One-, Two-, and Three-Dimensional Alkaline Earth Metal Gallium Nitrides: Sr(3)Ga(2)N(4), Ca(3)Ga(2)N(4), and Sr(3)Ga(3)N(5).

Abstract:

We report the structures of three new alkaline earth metal gallium nitrides synthesized as crystals from the elements in sealed Nb tubes at 760 degrees C using Na/Sr and Na/Ca melts as growth media. The materials are all transparent insulators. Yellow Sr(3)Ga(2)N(4) is isostructural with the previously reported Ba(3)Ga(2)N(4) and Sr(3)Al(2)N(4). It crystallizes in Pnna (No. 52) with a = 5.9552(6) Å, b = 10.2753(8) Å, c = 9.5595(9) Å, and Z = 4. It contains infinite chains, [GaN(4/2)(3)(-)], o...

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Publication status:
Published

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Publisher copy:
10.1021/ic9612562

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Inorganic chemistry More from this journal
Volume:
36
Issue:
6
Pages:
1143-1148
Publication date:
1997-03-01
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
Language:
English
Pubs id:
pubs:46243
UUID:
uuid:ad9895c3-c865-4ff6-9373-784dd99bcf34
Local pid:
pubs:46243
Source identifiers:
46243
Deposit date:
2012-12-19

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