Journal article icon

Journal article

Unexpected interactions between alkyl straps and pyridine ligands in sulfur-strapped porphyrin nanorings

Abstract:

Strapped or "basket-handle" porphyrins have been investigated previously as hemoglobin mimics and catalysts. The facial selectivity of their interactions with axial ligands is a sensitive test for noncovalent bonding. Here the binding of pyridyl ligands to zinc porphyrins with thioester-linked alkyl straps is investigated in solution by NMR spectroscopy and UV-vis titration, and in the solid state by X-ray crystallography. We expected that coordination of the axial ligand would occur on the l...

Expand abstract
Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher's version

Actions


Access Document


Files:
Publisher copy:
10.1021/acs.joc.7b01128

Authors


More by this author
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Role:
Author
More by this author
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Role:
Author
More by this author
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Role:
Author
Expand authors...
Templeton World Charity Foundation More from this funder
Publisher:
American Chemical Society Publisher's website
Journal:
Journal of Organic Chemistry Journal website
Volume:
82
Issue:
14
Pages:
7446–7462
Publication date:
2017-07-07
DOI:
EISSN:
1520-6904
ISSN:
0022-3263
Pubs id:
pubs:708046
URN:
uri:ad8f802e-6036-4470-a39a-f317e05f3a94
UUID:
uuid:ad8f802e-6036-4470-a39a-f317e05f3a94
Local pid:
pubs:708046
Paper number:
14
Language:
English
Keywords:

Terms of use


Metrics


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP