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Absolute electron impact ionization cross-sections and polarizability volumes for the C-2 to C-6 methanoates and C-3 to C-7 ethanoates

Abstract:

Absolute total positive ion electron impact ionization cross-sections from 15 to 285 eV are reported for the C2 to C6 methanoates (formates) and the C3 to C7 ethanoates (acetates), including all isomers. The reproducibility of the measured cross-sections over the full energy range is better than ±4%, and absolute cross-sections measured for a series of reference species (N2 and inert gases) are in excellent agreement with values reported by several other groups claiming accuracies of around ±...

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Publication status:
Published

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Publisher copy:
10.1016/j.ijms.2005.11.003

Authors


Hudson, JE More by this author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Harland, PW More by this author
Journal:
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY
Volume:
248
Issue:
1-2
Pages:
42-46
Publication date:
2006
DOI:
ISSN:
1387-3806
URN:
uuid:ad8cf817-792b-4f21-b176-397f870c338a
Source identifiers:
59446
Local pid:
pubs:59446

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