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Absolute electron impact ionization cross-sections and polarizability volumes for the C-2 to C-6 methanoates and C-3 to C-7 ethanoates

Abstract:

Absolute total positive ion electron impact ionization cross-sections from 15 to 285 eV are reported for the C2 to C6 methanoates (formates) and the C3 to C7 ethanoates (acetates), including all isomers. The reproducibility of the measured cross-sections over the full energy range is better than ±4%, and absolute cross-sections measured for a series of reference species (N2 and inert gases) are in excellent agreement with values reported by several other groups claiming accuracies of around ±...

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Publication status:
Published

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Publisher copy:
10.1016/j.ijms.2005.11.003

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY
Volume:
248
Issue:
1-2
Pages:
42-46
Publication date:
2006-01-01
DOI:
ISSN:
1387-3806
Language:
English
Keywords:
Pubs id:
pubs:59446
UUID:
uuid:ad8cf817-792b-4f21-b176-397f870c338a
Local pid:
pubs:59446
Source identifiers:
59446
Deposit date:
2012-12-19

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