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THE ELECTROCHEMISTRY OF [PTH(PET3)3]+ - INVERTED AND AMPLIFIED CYCLIC VOLTAMMETRIC WAVES AND CATALYTIC HYDROGEN-PRODUCTION AT A MERCURY-ELECTRODE

Abstract:

Inverted and amplified waves in cyclic voltammograms of [PtH(PEt3)3]+ at a sitting mercury drop electrode are interpreted in terms of catalytic cycles for hydrogen production from water involving adsorbed species. The adsorption step on the cathodic sweep involves a two-electron reduction to the catalytically inactive species [PtH(PEt3)3]- (ads.). On the reverse (anodic) sweep, a reductive catalytic cycle is initiated by oxidation to [PtH(PEt3)3]. (ads.) and stops when the potential is insuff...

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Publication status:
Published

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Publisher copy:
10.1039/dt9860001225

Authors


COMPTON, R More by this author
COLEHAMILTON, D More by this author
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
Issue:
6
Pages:
1225-1229
Publication date:
1986-06-05
DOI:
EISSN:
1364-5447
ISSN:
0300-9246
URN:
uuid:ad7fbc7e-2dc9-4271-aa77-61ce1067735e
Source identifiers:
42556
Local pid:
pubs:42556
Language:
English

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