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Oxidative bond formation and reductive bond cleavage at main group metal centers: reactivity of five-valence-electron MX₂ radicals.

Abstract:
Monomeric five-valence-electron bis(boryl) complexes of gallium, indium, and thallium undergo oxidative M-C bond formation with 2,3-dimethylbutadiene, in a manner consistent with both the redox properties expected for M(II) species and with metal-centered radical character. The weaker nature of the M-C bond for the heavier two elements leads to the observation of reversibility in M-C bond formation (for indium) and to the isolation of products resulting from subsequent B-C reductive elimination (for both indium and thallium).
Publication status:
Published

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Publisher copy:
10.1021/ja5062467

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Publisher:
American Chemical Society
Journal:
Journal of the American Chemical Society More from this journal
Volume:
136
Issue:
31
Pages:
10902-10905
Publication date:
2014-08-01
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
Language:
English
Pubs id:
pubs:476244
UUID:
uuid:ad58793b-e072-432f-9615-9e720ea118a8
Local pid:
pubs:476244
Source identifiers:
476244
Deposit date:
2014-08-12

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