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THE PHOTO-ISOMERIZATION OF CIS-AZOBENZENE - A CHANNEL ELECTRODE STUDY

Abstract:

The photo-isomerisation of cis-azobenzene by light of wavelength 432 nm has been investigated by channel electrode voltammetry. In a lithium ethoxide/ethanol medium cis-azobenzene was found to be reduced at a more positive potential (ca. 120 mV) than the trans isomer in the dark at a gold electrode. Quantitative waveshape measurements, with the electrode illuminated, of current-voltage curves for the reduction of the cis isomer as a function of the rate of mass transport, reveal the partial c...

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Publication status:
Published

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Journal:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume:
322
Issue:
1-2
Pages:
183-190
Publication date:
1992-01-10
DOI:
ISSN:
0022-0728
Source identifiers:
43801
Language:
English
Pubs id:
pubs:43801
UUID:
uuid:ad00694d-7c39-4d8a-8b2e-392eebb0919e
Local pid:
pubs:43801
Deposit date:
2012-12-19

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