Journal article icon

Journal article

Transient EPR Reveals Triplet State Delocalization in a Series of Cyclic and Linear π-Conjugated Porphyrin Oligomers

Abstract:

The photoexcited triplet states of a series of linear and cyclic butadiyne-linked porphyrin oligomers were investigated by transient Electron Paramagnetic Resonance (EPR) and Electron Nuclear DOuble Resonance (ENDOR). The spatial delocalization of the triplet state wave function in systems with different numbers of porphyrin units and different geometries was analyzed in terms of zero-field splitting parameters and proton hyperfine couplings. Even though no significant change in the zero-fiel...

Expand abstract
Publication status:
Published
Peer review status:
Peer reviewed
Version:
Accepted manuscript

Actions


Access Document


Files:
Publisher copy:
10.1021/jacs.5b04511

Authors


More by this author
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Role:
Author
More by this author
Department:
New College
Role:
Author
Engineering and Physical Sciences Research Council More from this funder
Publisher:
American Chemical Society Publisher's website
Journal:
Journal of the American Chemical Society Journal website
Volume:
137
Issue:
25
Pages:
8284-8293
Publication date:
2015-06-02
DOI:
EISSN:
1520-5126
ISSN:
0002-7863
Pubs id:
pubs:527708
URN:
uri:acae16c0-6486-446c-b05e-21468abf1b8a
UUID:
uuid:acae16c0-6486-446c-b05e-21468abf1b8a
Local pid:
pubs:527708
Paper number:
25
Language:
English
Keywords:

Terms of use


Metrics


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP