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Journal article

4-Methoxy-phenyl 2,3,4,6-tetra-O-acetyl-1-thio-α-d-mannopyran-oside.

Abstract:
The title compound, C(21)H(26)O(10)S, was synthesized in a single step from mannose penta-acetate. The mol-ecular structure confirms the α configuration of the anomeric thioaryl substituent. Spectroscopic and melting-point data obtained for the title compound are in disagreement with those previously reported, indicating the previously reported synthesis [Durette and Shen (1980 ▶). Carbohydr. Res. 81, 261-274] to be erroneous. The crystal structure is stabilized by weak inter-molecular C-H⋯O hydrogen bonds.
Publication status:
Published

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Publisher copy:
10.1107/s1600536808019338

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Acta crystallographica. Section E, Structure reports online
Volume:
64
Issue:
Pt 8
Pages:
o1401
Publication date:
2008-01-01
DOI:
EISSN:
1600-5368
ISSN:
1600-5368
Source identifiers:
117184
Language:
English
Pubs id:
pubs:117184
UUID:
uuid:ac785e6d-db0a-4a22-9c6c-cf0300668207
Local pid:
pubs:117184
Deposit date:
2012-12-19

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