Journal article
4-Methoxy-phenyl 2,3,4,6-tetra-O-acetyl-1-thio-α-d-mannopyran-oside.
- Abstract:
- The title compound, C(21)H(26)O(10)S, was synthesized in a single step from mannose penta-acetate. The mol-ecular structure confirms the α configuration of the anomeric thioaryl substituent. Spectroscopic and melting-point data obtained for the title compound are in disagreement with those previously reported, indicating the previously reported synthesis [Durette and Shen (1980 ▶). Carbohydr. Res. 81, 261-274] to be erroneous. The crystal structure is stabilized by weak inter-molecular C-H⋯O hydrogen bonds.
- Publication status:
- Published
Actions
Authors
- Journal:
- Acta crystallographica. Section E, Structure reports online More from this journal
- Volume:
- 64
- Issue:
- Pt 8
- Pages:
- o1401
- Publication date:
- 2008-01-01
- DOI:
- EISSN:
-
1600-5368
- ISSN:
-
1600-5368
- Language:
-
English
- Pubs id:
-
pubs:117184
- UUID:
-
uuid:ac785e6d-db0a-4a22-9c6c-cf0300668207
- Local pid:
-
pubs:117184
- Source identifiers:
-
117184
- Deposit date:
-
2012-12-19
Terms of use
- Copyright date:
- 2008
If you are the owner of this record, you can report an update to it here: Report update to this record