Journal article
Mapping the ionic fingerprints of molecular monolayers.
- Abstract:
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We have previously proposed, and experimentally resolved, an ionic charge relaxation model for redox inactive self-assembled monolayers (SAMs) on metallic electrodes in contact with a liquid electrolyte. Here we analyse, by capacitance spectroscopy, the resistance and capacitance terms presented by a range of thiolated molecular films. Molecular dynamics simulations support a SAM-specific energy barrier to solution-phase ions. Once surmounted, the entrapped ions support a film embedded ionic ...
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- Publication status:
- Published
- Peer review status:
- Peer reviewed
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- Files:
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(Accepted manuscript, pdf, 2.0MB)
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- Publisher copy:
- 10.1039/c7cp01500c
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Authors
Funding
São Paulo Research Foundation
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Royal Society
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Brazilian National Counsel of Technological and Scientific Development
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Bibliographic Details
- Publisher:
- Royal Society of Chemistry Publisher's website
- Journal:
- Physical Chemistry Chemical Physics Journal website
- Volume:
- 19
- Pages:
- 15098-15109
- Publication date:
- 2017-05-12
- Acceptance date:
- 2017-05-12
- DOI:
- EISSN:
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1463-9076
- ISSN:
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1463-9084
- Source identifiers:
-
698049
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:698049
- UUID:
-
uuid:ac3ce330-b450-4c34-93de-bc93605af357
- Local pid:
- pubs:698049
- Deposit date:
- 2017-06-07
Terms of use
- Copyright holder:
- Owner Societies
- Copyright date:
- 2017
- Notes:
- © the Owner Societies 2017. This is the accepted manuscript version of the article. The final version is available online from Royal Society of Chemistry at: http://dx.doi.org/10.1039/c7cp01500
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