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C-C Bond Activation of a Cyclopropyl Phosphine: Isolation and Reactivity of a Tetrameric Rhodacyclobutane

Abstract:

Reaction of the functionalized phosphine P tBu 2CH 2(C 3H 5) with [Rh(C 8H 14) 2Cl] 2 (C 8H 14 = cis-cyclooctene) resulted in selective C-C bond activation of the cyclopropyl group and formation of a tetrameric rhodacyclobutane, [R...

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Publication status:
Published

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Publisher copy:
10.1021/om100105p

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
ORGANOMETALLICS More from this journal
Volume:
29
Issue:
10
Pages:
2332-2342
Publication date:
2010-05-24
DOI:
EISSN:
1520-6041
ISSN:
0276-7333
Language:
English
Pubs id:
pubs:58670
UUID:
uuid:abf63f16-22db-4907-ad67-ed3f588d0fd0
Local pid:
pubs:58670
Source identifiers:
58670
Deposit date:
2012-12-19

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