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Hydroboration of an alkene by amine-boranes catalysed by a [Rh(PR3)2]+ fragment. Mechanistic insight and tandem hydroboration/dehydrogenation.

Abstract:
The catalytic hydroboration of tert-butylethene using H(3)B·NMe(3) gives RH(2)B·NMe(3). With H(3)B·NMe(2)H tandem hydroboration under mild conditions/dehydrocoupling occurs that produces R(2)B=NMe(2) (R = H, CH(2)CH(2)(t)Bu).
Publication status:
Published

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Publisher copy:
10.1039/c1dt10819k

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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Role:
Author
Journal:
Dalton transactions (Cambridge, England : 2003)
Volume:
40
Issue:
29
Pages:
7499-7501
Publication date:
2011-08-05
DOI:
EISSN:
1477-9234
ISSN:
1477-9226
URN:
uuid:abc673ad-2241-4afe-9216-edce5491cef0
Source identifiers:
163947
Local pid:
pubs:163947
Language:
English
Keywords:

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