- Abstract:
- The catalytic hydroboration of tert-butylethene using H(3)B·NMe(3) gives RH(2)B·NMe(3). With H(3)B·NMe(2)H tandem hydroboration under mild conditions/dehydrocoupling occurs that produces R(2)B=NMe(2) (R = H, CH(2)CH(2)(t)Bu).
- Publication status:
- Published
- Publisher copy:
- 10.1039/c1dt10819k
-
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- Journal:
- Dalton transactions (Cambridge, England : 2003)
- Volume:
- 40
- Issue:
- 29
- Pages:
- 7499-7501
- Publication date:
- 2011-08-05
- DOI:
- EISSN:
-
1477-9234
- ISSN:
-
1477-9226
- URN:
-
uuid:abc673ad-2241-4afe-9216-edce5491cef0
- Source identifiers:
-
163947
- Local pid:
- pubs:163947
- Copyright date:
- 2011
Journal article
Hydroboration of an alkene by amine-boranes catalysed by a [Rh(PR3)2]+ fragment. Mechanistic insight and tandem hydroboration/dehydrogenation.
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