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The Jahn-Teller distortion and cation ordering in the perovskite Sr2MnSbO6

Abstract:

The perovskite Sr2MnSbO6 has been synthesized using conventional ceramic techniques and structurally characterized using high-resolution powder X-ray and neutron diffraction. The structure is tetragonal in space group I 4 / m. The octahedra were found to feature Jahn-Teller (JT) distortion due to the presence of Mn3+, and this is identified as strongly contributing to the octahedral tilting. Evidence for B-site cation ordering is presented however there is extensive anti-site disorder. The di...

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Publisher copy:
10.1016/j.jssc.2006.03.013

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Journal of Solid State Chemistry
Volume:
179
Issue:
6
Pages:
1775-1781
Publication date:
2006-06-01
DOI:
EISSN:
1095-726X
ISSN:
0022-4596
Source identifiers:
284502
Language:
English
Keywords:
Pubs id:
pubs:284502
UUID:
uuid:ab5e5ca9-208f-4a04-aea1-59c91394ea4f
Local pid:
pubs:284502
Deposit date:
2013-11-17

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