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Voltammetric and electrochemical ESR studies of oxidation reactions mediated by tris(4-bromophenyl)amine in acetonitrile.

Abstract:

The electrochemical oxidation of tris(4-bromophenyl)amine in the presence of 2,6-lutidine is examined in acetonitrile. Voltammetric and spectroscopic investigations suggest that the electrogenerated triaryl aminium radical cation oxidizes 2,6-lutidine in an EC' mechanism, and an equilibrium constant for this homogeneous electron transfer is estimated. The mediated oxidation of a protected phenyl selenoglycoside by this reaction mixture is studied by the use of electrochemical ESR, employing a...

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Publication status:
Published

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Publisher copy:
10.1021/jp0535137

Authors


Streeter, I More by this author
Thompson, M More by this author
Fietkau, N More by this author
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Journal:
The journal of physical chemistry. B
Volume:
110
Issue:
6
Pages:
2681-2691
Publication date:
2006-02-05
DOI:
EISSN:
1520-5207
ISSN:
1520-6106
URN:
uuid:aaf4f147-8fbd-4eb7-b4a4-dc1bd086ca71
Source identifiers:
33384
Local pid:
pubs:33384

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