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Journal article

A novel coordination mode for pentalene in trinuclear chromium complexes.

Abstract:
The first chromium pentalene complexes have been characterized; in these the ligand displays a hitherto-unknown bonding mode whereby a dimeric [Cr(Cp*)](2)(mu-OR) unit is bound (mu:eta(2):eta(2))- to one face, and Cp*Cr is bound eta(5)- to the other. The magnetic properties of these compounds can be understood as the superposition of those of a chromocene and an antiferromagnetically coupled Cr[bond]Cr bonded unit.
Publication status:
Published

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Publisher copy:
10.1021/ic0350887

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Inorganic chemistry More from this journal
Volume:
42
Issue:
24
Pages:
7707-7709
Publication date:
2003-12-01
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
Language:
English
Pubs id:
pubs:51191
UUID:
uuid:aaa42dea-95c6-4f05-8377-2a490bc6e027
Local pid:
pubs:51191
Source identifiers:
51191
Deposit date:
2012-12-19

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