- Abstract:
- Dicarbonyl-stabilised diazo functionality is tolerated during alkene cross-metathesis using Grubbs' catalyst, but undergoes subsequent tandem carbonyl ylide formation-intramolecular 1,3-dipolar cycloaddition on addition of catalytic Rh2(OAc)4 in a one-pot operation.
- Publication status:
- Published
- Publisher copy:
- 10.1039/b515943a
-
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- Journal:
- Chemical communications (Cambridge, England)
- Volume:
- 6
- Issue:
- 6
- Pages:
- 627-628
- Publication date:
- 2006-02-05
- DOI:
- EISSN:
-
1364-548X
- ISSN:
-
1359-7345
- URN:
-
uuid:aa931daa-f426-452a-bc48-426d47ca441c
- Source identifiers:
-
33373
- Local pid:
- pubs:33373
- Language:
- English
- Copyright date:
- 2006
Journal article
One-pot cross-metathesis/tandem carbonyl ylide formation-intramolecular cycloaddition of an unsaturated 2-diazo-3,6-diketoester.
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