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POTENTIAL-ENERGY SURFACE EFFECTS ON DIFFERENTIAL CROSS-SECTIONS FOR POLYATOMIC REACTIONS

Abstract:

The effect on differential and integral cross sections of varying the potential energy of the entrance channel to a polyatomic reaction is investigated theoretically. The rotating bond approximation (RBA) is used for the CH4+OH → CH3+H2O reaction. The reaction exhibits peripheral dynamics, with a higher reactivity at higher impact parameters. Due to the significant potential barrier the scattering of the products is however sideways and not forward. It is found that varying the long-range iso...

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Publication status:
Published

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Journal:
CHEMICAL PHYSICS
Volume:
191
Issue:
1-3
Pages:
223-233
Publication date:
1995-02-01
DOI:
ISSN:
0301-0104
URN:
uuid:aa7c0d30-2a66-448c-afe3-64d5aa24ad4d
Source identifiers:
52987
Local pid:
pubs:52987
Language:
English

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