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Journal article

Synthesis, structures and reactivity of group 4 hydrazido complexes supported by calix[4]arene ligands.

Abstract:

Reaction of TiCl(2)(Me(2)Calix) with 2 equiv of LiNHNRR' afforded the corresponding terminal hydrazido(2-) complexes Ti(NNRR')(Me(2)Calix) (R = Ph, R' = Ph (1) or Me; R = R' = Me (3)) which were all structurally characterized. The X-ray structure of Ph(2)NNH(2) is reported for comparison. Compound 1 was also prepared from Na(2)[Me(2)Calix] and Ti(NNPh(2))Cl(2)(py)(3). Reaction of ZrCl(2)(Me(2)Calix) with 2 equiv of LiNHNR(2) afforded only the bis(hydrazido(1-)) complexes Zr(NHNR(2))(2)(Me(2)C...

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Publication status:
Published

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Publisher copy:
10.1021/ic801735c

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
Journal:
Inorganic chemistry More from this journal
Volume:
47
Issue:
24
Pages:
12049-12062
Publication date:
2008-12-01
DOI:
EISSN:
1520-510X
ISSN:
0020-1669
Language:
English
Keywords:
Pubs id:
pubs:51058
UUID:
uuid:aa298212-a506-43e9-a8f7-41bc1d0c813a
Local pid:
pubs:51058
Source identifiers:
51058
Deposit date:
2012-12-19

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