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Molecular aluminum hydrides identified by inelastic neutron scattering during H2 regeneration of catalyst-doped NaAlH4.

Abstract:

Catalyst-doped sodium aluminum hydrides have been intensively studied as solid hydrogen carriers for onboard proton-exchange membrane (PEM) fuel cells. Although the importance of catalyst choice in enhancing kinetics for both hydrogen uptake and release of this hydride material has long been recognized, the nature of the active species and the mechanism of catalytic action are unclear. We have shown by inelastic neutron scattering (INS) spectroscopy that a volatile molecular aluminum hydride ...

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Publication status:
Published

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Publisher copy:
10.1021/jp055238u
Journal:
journal of physical chemistry. B
Volume:
110
Issue:
2
Pages:
711-715
Publication date:
2006-01-01
DOI:
EISSN:
1520-5207
ISSN:
1520-6106
Language:
English
Pubs id:
pubs:51502
UUID:
uuid:aa1861d9-218a-40ef-a04d-b107f4fa3363
Local pid:
pubs:51502
Source identifiers:
51502
Deposit date:
2012-12-19

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