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Switching the structural force in ionic liquid–solvent mixtures by varying composition

Abstract:

The structure and interactions in electrolytes at high concentration have implications from energy storage to biomolecular interactions. However many experimental observations are yet to be explained in these mixtures, which are far beyond the regime of validity of mean-field models. Here, we study the structural forces in a mixture of ionic liquid and solvent that is miscible in all proportions at room temperature. Using the surface force balance to measure the force between macroscopic smoo...

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Publication status:
Published
Peer review status:
Peer reviewed
Version:
Publisher version

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Publisher copy:
10.1103/PhysRevLett.118.096002

Authors


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Department:
Trinity College
Role:
Author
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Funding agency for:
Perkin, S
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Grant:
UK-US Fulbright Fellowship
Publisher:
American Physical Society Publisher's website
Journal:
Physical Review Letters Journal website
Volume:
118
Issue:
9
Pages:
Article: 096002
Publication date:
2017-03-03
Acceptance date:
2017-02-07
DOI:
EISSN:
1079-7114
Pubs id:
pubs:677363
URN:
uri:a9f9bf3e-ef4b-4ab9-9ede-6182f98cfba1
UUID:
uuid:a9f9bf3e-ef4b-4ab9-9ede-6182f98cfba1
Local pid:
pubs:677363
Paper number:
9

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