Journal article
Acoustic phonons and negative thermal expansion in MOF-5.
- Abstract:
- The mechanism of negative thermal expansion (NTE) in MOF-5 has been studied using a rigid unit mode analysis of the phonons responsible for NTE. In addition to confirming the role of the previously proposed optic 'trampoline mode' mechanism [Lock et al., Dalton Trans., 2013, 42, 1933-2320], we have identified a new acoustic mode mechanism that makes a major contribution to the macroscopic NTE of this framework.
- Publication status:
- Published
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Bibliographic Details
- Publisher:
- Royal Society of Chemistry
- Journal:
- Physical chemistry chemical physics : PCCP
- Volume:
- 16
- Issue:
- 39
- Pages:
- 21144-21152
- Publication date:
- 2014-10-01
- DOI:
- EISSN:
-
1463-9084
- ISSN:
-
1463-9076
Item Description
- Language:
- English
- Pubs id:
-
pubs:480082
- UUID:
-
uuid:a9d1c77c-8677-4203-86d5-f09717711285
- Local pid:
- pubs:480082
- Source identifiers:
-
480082
- Deposit date:
- 2014-08-17
Terms of use
- Copyright date:
- 2014
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