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Behavior of the heterogeneous electron-transfer rate constants of arenes and substituted anthracenes in room-temperature ionic liquids

Abstract:

We report the anodic oxidation of several arenes and anthracenes within room-temperature ionic liquids (RTILs). In particular, the heterogeneous electron-transfer rates (k0) for substituted anthracenes and arenes are also investigated in 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([C2mim][NTf2]) and found not to obey the outer-sphere Marcus-type behavior of these compounds in contrast to the behavior in traditional organic solvents, in particular the predictions for k0 with...

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Publication status:
Published

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Publisher copy:
10.1021/jp7103598

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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
JOURNAL OF PHYSICAL CHEMISTRY C
Volume:
112
Issue:
5
Pages:
1650-1657
Publication date:
2008-02-07
DOI:
EISSN:
1932-7455
ISSN:
1932-7447
Source identifiers:
118924
Language:
English
Pubs id:
pubs:118924
UUID:
uuid:a9c2073d-7d82-4572-92d1-cde5f16f053e
Local pid:
pubs:118924
Deposit date:
2012-12-19

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