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The effect of pressure on Cu-btc: framework compression vs. guest inclusion.

Abstract:
Here we present detailed structural data on the effect of high pressure on Cu-btc. Application of pressure causes solvent to be squeezed into the pores until a phase transition occurs, driven by the sudden compression and expansion of equatorial and axial Cu-O bonds.
Publication status:
Published

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Publisher copy:
10.1039/c1cc16045a

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Institution:
University of Oxford
Division:
MPLS
Department:
Engineering Science
Role:
Author
Journal:
Chemical Communications
Volume:
48
Issue:
10
Pages:
1535-1537
Publication date:
2012-02-01
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Source identifiers:
369789
Language:
English
Pubs id:
pubs:369789
UUID:
uuid:a8dae38b-9002-4a37-9d4a-11bd01243e85
Local pid:
pubs:369789
Deposit date:
2013-11-16

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