- Abstract:
-
Members of a family of functionally and stereochemically diverse d-glucosamine-derived tertiary aminoalcohol ligands have been used to promote the asymmetric Reformatsky reaction. The β-hydroxyester product tert-butyl 3-phenyl-3-hydroxy-propanoate was obtained enriched in either the (+)-(R) (up to 74% ee) or (-)-(S) (up to 42% ee) enantiomer depending on the choice of ligand. Although the selectivities are modest in absolute terms they represent some the better selectivities obtained to date ...
Expand abstract - Publication status:
- Published
- Publisher copy:
- 10.1016/j.tetasy.2004.11.049
-
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- Journal:
- TETRAHEDRON-ASYMMETRY
- Volume:
- 16
- Issue:
- 1
- Pages:
- 213-221
- Publication date:
- 2005-01-10
- DOI:
- ISSN:
-
0957-4166
- URN:
-
uuid:a8c774cf-435c-4b9f-97bd-9a9c6c792569
- Source identifiers:
-
39332
- Local pid:
- pubs:39332
- Language:
- English
- Copyright date:
- 2005
Journal article
Carbohydrate-derived aminoalcohol ligands for asymmetric Reformatsky reactions
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