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Hybrid nanosheets of an inorganic-organic framework material: facile synthesis, structure, and elastic properties.

Abstract:

We report a new 2-D inorganic-organic framework material, MnDMS [Mn 2,2-dimethylsuccinate], featuring weakly bound hybrid layers in its bulk crystals that can be readily exfoliated into nanosheets via ultrasonication. The fully exfoliated hybrid nanosheets correspond to a unilamellar thickness of about 1 nm, while the partially exfoliated nanosheets (multilayer films) exhibit a typical thickness on the order of 10 nm. We used atomic force microscopy to characterize their surface topography an...

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Publication status:
Published

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Publisher copy:
10.1021/nn204054k

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Engineering Science
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Inorganic Chemistry
Bithell, EG More by this author
Cheetham, AK More by this author
Journal:
ACS nano
Volume:
6
Issue:
1
Pages:
615-621
Publication date:
2012-01-05
DOI:
EISSN:
1936-086X
ISSN:
1936-0851
URN:
uuid:a8c26e0f-3d22-4548-9521-2639586445d1
Source identifiers:
271495
Local pid:
pubs:271495

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