- Abstract:
- A series of single electron-transfer (SET) reactions on a naphthyl thioether have shown that the reductive cleavage mechanism changes at low temperatures and this selectivity is proved using an electrochemical analysis that mimics the SET reaction conditions.
- Publication status:
- Published
- Publisher copy:
- 10.1039/b606638k
-
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- Journal:
- Chemical communications (Cambridge, England)
- Issue:
- 32
- Pages:
- 3402-3404
- Publication date:
- 2006-08-05
- DOI:
- EISSN:
-
1364-548X
- ISSN:
-
1359-7345
- URN:
-
uuid:a8bbefd4-75d3-4d40-b9fb-fa8447870dc6
- Source identifiers:
-
33571
- Local pid:
- pubs:33571
- Language:
- English
- Copyright date:
- 2006
Journal article
Cryovoltammetrically probing functional group reductive cleavage: alkyl-sulfur versus aryl-sulfur bond cleavage in an alkyl naphthyl thioether under single electron-transfer is temperature switchable.
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