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Cryovoltammetrically probing functional group reductive cleavage: alkyl-sulfur versus aryl-sulfur bond cleavage in an alkyl naphthyl thioether under single electron-transfer is temperature switchable.

Abstract:
A series of single electron-transfer (SET) reactions on a naphthyl thioether have shown that the reductive cleavage mechanism changes at low temperatures and this selectivity is proved using an electrochemical analysis that mimics the SET reaction conditions.
Publication status:
Published

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Publisher copy:
10.1039/b606638k

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Journal:
Chemical Communications
Issue:
32
Pages:
3402-3404
Publication date:
2006-08-01
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
Source identifiers:
33571
Language:
English
Pubs id:
pubs:33571
UUID:
uuid:a8bbefd4-75d3-4d40-b9fb-fa8447870dc6
Local pid:
pubs:33571
Deposit date:
2012-12-19

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