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Cryovoltammetrically probing functional group reductive cleavage: alkyl-sulfur versus aryl-sulfur bond cleavage in an alkyl naphthyl thioether under single electron-transfer is temperature switchable.

Abstract:
A series of single electron-transfer (SET) reactions on a naphthyl thioether have shown that the reductive cleavage mechanism changes at low temperatures and this selectivity is proved using an electrochemical analysis that mimics the SET reaction conditions.
Publication status:
Published

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Publisher copy:
10.1039/b606638k

Authors


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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
Role:
Author
Journal:
Chemical communications (Cambridge, England)
Issue:
32
Pages:
3402-3404
Publication date:
2006-08-05
DOI:
EISSN:
1364-548X
ISSN:
1359-7345
URN:
uuid:a8bbefd4-75d3-4d40-b9fb-fa8447870dc6
Source identifiers:
33571
Local pid:
pubs:33571
Language:
English

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