- (Figure Presented) The carbon-phosphorus-antimony cage of P 2C2tBu2SbCl (see picture) adopts an envelope-type structure which is quite distinct from its phosphorus analogue, the tricyclic compound P2C2tBu2PCl. DFT calculations reveal that subtle changes in electronic structure as a result of the inert-pair effect lead to profound differences in structural and dynamic behavior. © 2006 Wiley-VCH Verlag GmbH and Co. KGaA.
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A main-group analogue of housene: the subtle influence of the inert-pair effect in group 15 clusters.
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