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A main-group analogue of housene: the subtle influence of the inert-pair effect in group 15 clusters.

Abstract:
(Figure Presented) The carbon-phosphorus-antimony cage of P 2C2tBu2SbCl (see picture) adopts an envelope-type structure which is quite distinct from its phosphorus analogue, the tricyclic compound P2C2tBu2PCl. DFT calculations reveal that subtle changes in electronic structure as a result of the inert-pair effect lead to profound differences in structural and dynamic behavior. © 2006 Wiley-VCH Verlag GmbH and Co. KGaA.
Publication status:
Published

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Publisher copy:
10.1002/anie.200601804

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Journal:
Angewandte Chemie (International ed. in English)
Volume:
45
Issue:
40
Pages:
6685-6689
Publication date:
2006-10-05
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
URN:
uuid:a88dbcc0-c2db-4b6b-bf88-05148bd20835
Source identifiers:
50429
Local pid:
pubs:50429

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