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Journal article

Selective electrochemical glycosylation by reactivity tuning.

Abstract:

Electrochemical glycosylation of a selenoglycoside donor proceeds efficiently in an undivided cell in acetonitrile to yield beta-glycosides. Measurement of cyclic voltammograms for a selection of seleno-, thio-, and O-glycosides indicates the dependence of oxidation potential on the anomeric substituent allowing the possibility for the rapid construction of oligosaccharides by selective electrochemical activation utilising variable cell potentials in combination with reactivity tuning of the ...

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Publication status:
Published

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Publisher copy:
10.1039/b316728c

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
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Journal:
Organic and biomolecular chemistry
Volume:
2
Issue:
15
Pages:
2195-2202
Publication date:
2004-08-01
DOI:
EISSN:
1477-0539
ISSN:
1477-0520
Source identifiers:
32800
Language:
English
Keywords:
Pubs id:
pubs:32800
UUID:
uuid:a8725d95-f032-4f54-851a-0949f0fd7192
Local pid:
pubs:32800
Deposit date:
2012-12-19

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