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Selective electrochemical glycosylation by reactivity tuning.

Abstract:

Electrochemical glycosylation of a selenoglycoside donor proceeds efficiently in an undivided cell in acetonitrile to yield beta-glycosides. Measurement of cyclic voltammograms for a selection of seleno-, thio-, and O-glycosides indicates the dependence of oxidation potential on the anomeric substituent allowing the possibility for the rapid construction of oligosaccharides by selective electrochemical activation utilising variable cell potentials in combination with reactivity tuning of the ...

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Publication status:
Published

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Publisher copy:
10.1039/b316728c

Authors


France, RR More by this author
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Physical and Theoretical Chem
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Institution:
University of Oxford
Department:
Oxford, MPLS, Chemistry, Organic Chemistry
Fairbanks, AJ More by this author
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Journal:
Organic and biomolecular chemistry
Volume:
2
Issue:
15
Pages:
2195-2202
Publication date:
2004-08-05
DOI:
EISSN:
1477-0539
ISSN:
1477-0520
URN:
uuid:a8725d95-f032-4f54-851a-0949f0fd7192
Source identifiers:
32800
Local pid:
pubs:32800

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