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Synthesis of (R)-{eta(6)-[O-methyl-N-(alpha-methylbenzyl)hydroxyamino]-benzene} chromium tricarbonyl via nucleophilic aromatic substitution of (eta(6)-fluorobenzene) chromium tricarbonyl

Abstract:
Chiral hydroxylamine chromium tricarbonyl complexes may be prepared in satisfactory to reasonable yieldvia nucleophilic aromatic substitution of the anion derived from N,O-substituted hydroxylamines and (η6-fluorobenzene) chromium tricarbonyl. The enantiomerically pure complex (R)-{η6-[O-methyl-N-(α-methylbenzyl)hydroxyamino]- benzene} chromium tricarbonyl 6a was characterised by X-ray crystallography.
Publication status:
Published

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Publisher copy:
10.1039/b107237b

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Organic Chemistry
Role:
Author
Journal:
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 More from this journal
Issue:
21
Pages:
2850-2855
Publication date:
2001-11-07
DOI:
EISSN:
1364-5463
ISSN:
1472-7781
Language:
English
Pubs id:
pubs:110596
UUID:
uuid:a85b0c4d-22fd-4d82-9784-cc0b978f292f
Local pid:
pubs:110596
Source identifiers:
110596
Deposit date:
2012-12-19

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