Journal article icon

Journal article

Quantifying the electrocatalytic turnover of vitamin B12-mediated dehalogenation on single soft nanoparticles.

Abstract:
We report the electrocatalytic dehalogenation of trichloroethylene by single soft nanoparticles of VB12 containing droplets, and find that the binding between Co (I), the reduced form of Co (III), and TCE is likely a chemically reversible process and in particular using this model system quantify the turnover number and the kinetics of catalytic reactions at individual single soft nanoparticles in real time.
Publication status:
Published
Peer review status:
Peer reviewed

Actions


Access Document


Files:
Publisher copy:
10.1002/anie.201510394

Authors


More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Physical & Theoretical Chem
Role:
Author
Publisher:
Wiley
Journal:
Angewandte Chemie (International ed. in English) More from this journal
Volume:
55
Issue:
7
Pages:
2545-2549
Publication date:
2016-01-25
Acceptance date:
2015-12-01
DOI:
EISSN:
1521-3773
ISSN:
1433-7851
Language:
English
Keywords:
Pubs id:
pubs:597989
UUID:
uuid:a855cbef-de6d-4dfd-9a71-730395e68f9a
Local pid:
pubs:597989
Source identifiers:
597989
Deposit date:
2016-04-01

Terms of use


Views and Downloads






If you are the owner of this record, you can report an update to it here: Report update to this record

TO TOP