Journal article
Quantifying the electrocatalytic turnover of vitamin B12-mediated dehalogenation on single soft nanoparticles.
- Abstract:
- We report the electrocatalytic dehalogenation of trichloroethylene by single soft nanoparticles of VB12 containing droplets, and find that the binding between Co (I), the reduced form of Co (III), and TCE is likely a chemically reversible process and in particular using this model system quantify the turnover number and the kinetics of catalytic reactions at individual single soft nanoparticles in real time.
- Publication status:
- Published
- Peer review status:
- Peer reviewed
Actions
Authors
Bibliographic Details
- Publisher:
- Wiley Publisher's website
- Journal:
- Angewandte Chemie (International ed. in English) Journal website
- Volume:
- 55
- Issue:
- 7
- Pages:
- 2545-2549
- Publication date:
- 2016-01-25
- Acceptance date:
- 2015-12-01
- DOI:
- EISSN:
-
1521-3773
- ISSN:
-
1433-7851
Item Description
- Language:
- English
- Keywords:
- Pubs id:
-
pubs:597989
- UUID:
-
uuid:a855cbef-de6d-4dfd-9a71-730395e68f9a
- Local pid:
- pubs:597989
- Source identifiers:
-
597989
- Deposit date:
- 2016-04-01
Terms of use
- Copyright date:
- 2016
- Notes:
- This is the accepted manuscript version of the article. The final version is available online from Wiley at: https://doi.org/10.1002/anie.201510394
Metrics
If you are the owner of this record, you can report an update to it here: Report update to this record