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Journal article

Titanium alkoxyimido (Ti=N-OR) complexes: reductive N-O bond cleavage at the boundary between hydrazide and peroxide ligands.

Abstract:: The first Group 4 alkoxyimido compounds are reported. The Ti=N-O(t)Bu group in Ti(N(2)N(Me))(NO(t)Bu)(py) undergoes facile 2-electron N-O bond cleavage with PhCCMe as the reductant to form a 1,2-diamidoalkene group via two highly selective N-C bond forming events.

Publication status:: Published

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APA Style

Schwarz, A., Nova, A., Clot, E., & Mountford, P. (2011). Titanium alkoxyimido (Ti=N-OR) complexes: reductive N-O bond cleavage at the boundary between hydrazide and peroxide ligands. Chemical Communications, 47(17), 4926–4928.

MLA Style

Schwarz, A., et al. “Titanium Alkoxyimido (Ti=N-OR) Complexes: Reductive N-O Bond Cleavage at the Boundary between Hydrazide and Peroxide Ligands.” Chemical Communications, vol. 47, no. 17, 2011, pp. 4926–28.

Chicago Style

Schwarz, A, A Nova, E Clot, and P Mountford. 2011. “Titanium Alkoxyimido (Ti=N-OR) Complexes: Reductive N-O Bond Cleavage at the Boundary between Hydrazide and Peroxide Ligands.” Chemical Communications 47 (17): 4926–28.
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Publisher copy:: 10.1039/c1cc10862j

Authors

+ Schwarz, A More by this author

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Author

+ Nova, A More by this author

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Author

+ Clot, E More by this author

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+ Mountford, P More by this author

Institution:

University of Oxford

Division:

MPLS

Department:

Chemistry

Sub department:

Inorganic Chemistry

Role:

Author

Bibliographic Details

Journal:: Chemical Communications
Volume:: 47
Issue:: 17
Pages:: 4926-4928
Publication date:: 2011-05-01
DOI:: 10.1039/c1cc10862j
EISSN:: 1364-548X
ISSN:: 1359-7345

Item Description

Language:: English
Pubs id:: pubs:127203
UUID:: uuid:a8366bfb-b830-4665-bac6-a5fe3dce0ce2
Local pid:: pubs:127203
Source identifiers:: 127203
Deposit date:: 2012-12-19

Terms of use

Copyright date:: 2011

Licence:: Terms and Conditions of Use for Oxford University Research Archive

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