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On the ambiphilic reactivity of geometrically constrained phosphorus(III) and arsenic(III) compounds: Insights into their interaction with ionic substrates.

Abstract:

The ambiphilic nature of geometrically constrained Group 15 complexes bearing the N,N-bis(3,5-di-tert-butyl-2-phenolate)amide pincer ligand (ONO(3-) ) is explored. Despite their differing reactivity towards nucleophilic substrates with polarised element-hydrogen bonds (e.g., NH3 ), both the phosphorus(III), P(ONO) (1 a), and arsenic(III), As(ONO) (1 b), compounds exhibit similar reactivity towards charged nucleophiles and electrophiles. Reactions of 1 a and 1 b with KOtBu or KNPh2 afford anio...

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Publication status:
Published
Peer review status:
Peer reviewed

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Publisher copy:
10.1002/chem.201603135

Authors


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Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Division:
MPLS
Department:
Chemistry
Sub department:
Inorganic Chemistry
Role:
Author
More by this author
Institution:
University of Oxford
Oxford college:
Queens College
Role:
Author
More by this author
Institution:
University of Oxford
Oxford college:
Lady Margaret Hall
Role:
Author
More from this funder
Name:
Engineering and Physical Sciences Research Council
Grant:
EP/K039954/1
Publisher:
Wiley
Journal:
Chemistry: A European Journal More from this journal
Volume:
22
Issue:
44
Pages:
15712-15724
Publication date:
2016-09-01
Acceptance date:
2016-08-02
DOI:
ISSN:
1521-3765 and 0947-6539
Pmid:
27628576
Language:
English
Keywords:
Pubs id:
pubs:645947
UUID:
uuid:a80d6b8d-6062-45f4-9a53-d11df0182495
Local pid:
pubs:645947
Source identifiers:
645947
Deposit date:
2017-03-02

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